VRFBs currently show higher upfront CAPEX per kWh but excellent cycle life (>12,000–20,000 cycles) and minimal capacity fade; iron flow systems target lower material costs but face efficiency and system complexity trade-offs. . Lithium-ion batteries dominate short-duration storage, but their economics and degradation profile become challenging beyond 4–6 hours. Flow batteries—where energy and power are decoupled via liquid electrolytes—are emerging as candidates for 8–20+ hour long-duration energy storage (LDES). Definition and principles of flow batteries Flow battery. . Iron flow batteries are generally less mature in their development compared to vanadium flow batteries, which means their long-term lifespan is not as well-documented. In terms of critical raw materials and geopolitical concerns, the use of inexpensive and abundantly available. .
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